Nitrogen-Enriched Biguanidine-Functionalized Cobalt Ferrite Nanoparticles as a Heterogeneous Base Catalyst for Knoevenagel Condensation under Solvent-Free Conditions

نویسندگان

چکیده

Designing efficient, economical heterogeneous catalysts for the Knoevenagel condensation reaction is highly significant owing to importance of products in industries as well pharmaceutics. Herein, we have designed and synthesized biguanidine-functionalized basic magnetically retrievable cobalt ferrite nanoparticles (CFNPs) synthesis using benzaldehydes active methylene compounds (malononitrile/ethyl cyanoacetate/cyanoacetamide). Several advanced techniques, such Fourier transform infrared (FT-IR), thermogravimetric analysis (TGA), powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission (TEM), vibration sample magnetometry (VSM), were utilized precisely characterize catalyst. The robust features current approach involve outstanding catalytic performance, solvent-free conditions, ease catalyst retrievability, easy workup procedure, large substrate tolerance, high turnover frequency (TOF) values (up 486.88 h–1), green chemistry metrics E-factor (0.15), mass efficiency (RME) value (87.07%), carbon (93.4%), atom economy (AE) (88.10%) close their ideal values, recyclability up eight runs without a considerable reduction activity, boosting appeal this from commercial ecological point view.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A new application of nano-graphene oxide as a heterogeneous catalyst in crossed-aldol condensation reaction under solvent-free conditions

Nano-graphene oxide was synthesized by the oxidation of graphite powders. The structural nature of the nano-graphene oxide was characterized by a variety of techniques including XRD, TEM, FT-IR and UV/Vis. The functional groups on its basal planes and edges of nano-grahene oxide play important role in catalytic activity. The catalytic activity of nano-graphene oxide was investigated on Crossed-...

متن کامل

A new application of nano-graphene oxide as a heterogeneous catalyst in crossed-aldol condensation reaction under solvent-free conditions

Nano-graphene oxide was synthesized by the oxidation of graphite powders. The structural nature of the nano-graphene oxide was characterized by a variety of techniques including XRD, TEM, FT-IR and UV/Vis. The functional groups on its basal planes and edges of nano-grahene oxide play important role in catalytic activity. The catalytic activity of nano-graphene oxide was investigated on Crossed-...

متن کامل

a new application of nano-graphene oxide as a heterogeneous catalyst in crossed-aldol condensation reaction under solvent-free conditions

nano-graphene oxide was synthesized by the oxidation of graphite powders. the structural nature of the nano-graphene oxide was characterized by a variety of techniques including xrd, tem, ft-ir and uv/vis. the functional groups on its basal planes and edges of nano-grahene oxide play important role in catalytic activity. the catalytic activity of nano-graphene oxide was investigated on crossed-...

متن کامل

Dipyridine cobalt chloride as an efficient and chemoselective catalyst for the synthesis of 1,1-diacetates under solvent-free conditions

1,1-Diacetates(acylals) were prepared by direct condensation of various aldehydes with acetic anhydride using dipyridine cobalt chloride (CoPy2Cl2) as an efficient and green catalyst under solvent-free conditions at room temperature. The important features of this catalyst method are that the catalyst is solid, stable at high temperatures, soluble in water, stable in air, immiscible in common o...

متن کامل

Chitosan as a Renewable Heterogeneous Catalyst for the Knoevenagel Reaction in Ionic Liquid as Green Solvent

The combination of chitosan as a renewable heterogeneous catalyst and ionic liquid as a "green" solvent was employed for the Knoevenagel reaction. The chitosan catalyst was characterized by various techniques, including X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared spectros...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: ACS Organic & Inorganic Au

سال: 2023

ISSN: ['2694-247X']

DOI: https://doi.org/10.1021/acsorginorgau.3c00002